KNNS-BNZH Lead-Free 1–3 Piezoelectric Composite for Ultrasonic and Photoacoustic Imaging

摘要

In this paper, lead-free 0.965(K0.45Na0.55) (Nb0.96Sb0.04)O-3-0.0375Bi(0.5)Na(0.5)Zr(0.85)Hf(0.15)O(3) (KNNS-BNZH)/ epoxy 1-3 composite was designed and fabricated with the dice-and-fill method. The composite material exhibited a high thickness electromechanical coupling coefficient (k(t) = 0.7), high piezoelectric constant (d(33) = 350 pC N-1), relatively low mechanical quality factor (Q(m) = 5), and relatively low acoustic impedance. An ultrasonic transducer with a center frequency of 5 MHz was produced based on the 1-3 KNNS-BNZH/epoxy composite, showing a broad bandwidth of 80% (-6 dB) and two-way insertion loss of -30 dB. Ultrasonic and photoacoustic images were further demonstrated. The outstanding performance of the 1-3 KNNS-BNZH/epoxy composite transducer competitive to Pb(Zr1-xTix)O-3 (PZT)-based transducers suggests that the lead-free material can serve as a promising alternative to Pb-based piezoelectric materials for ultrasonic applications.