Durability of reinforced PVC-P geomembranes installed in reservoirs in eastern Spain

摘要

The aim of this paper is to study the durability of polyvinyl chloride (PVC-P) geomembranes reinforced with a synthetic fabric in hydraulic works in the Spanish Mediterranean basin. Therefore, a set of six geomembranes installed in irrigation reservoirs for 18-31 years were analysed. The initial characteristics of the geomembranes were determined to verify fulfilment of the Spanish regulations in force at the time. The characteristics were then assessed, and the results were interpreted with reference to the loss of plasticisers, tensile characteristics, foldability at low temperatures, dynamic impact resistance, puncture resistance, seam strength, reflected optical microscopy (ROM) and scanning electron microscopy (SEM). Additionally, the identification of the plasticisers in the geomembranes involved Fourier transform infrared spectroscopy (FTIR), gas chromatography (GC) and mass spectrometry (MS) tests. For the analysed samples, the loss of plasticisers was significant, ranging from 71.0% to 84.3%. However, the tensile strength results indicated current, regular waterproof working performances in the reservoirs. The results suggest that the durability of PVC-P geomembranes is a function of the loss of plasticisers and the state of the synthetic reinforced fibres.