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Oxidation Behavior Of Sic/sic Composites For Helium Cooled Solid Breeder Blanket

机译:SiC / SiC复合材料在氦冷却固体饲养毯上的氧化行为

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摘要

In order to evaluate the oxidation behavior and mechanism of SiC/SiC composites with conventional pyrolitic graphite interface (PyC-SiC/SiC) and advanced multilayer interface (ML-SiC/SiC) in a HCSB blanket environment, a thermal gravimetric analysis (TGA) in He + O_2 environment at 1000℃ and 1200℃ was performed. The PyC-SiC/SiC at 1200℃ and the ML-SiC/SiC at 1000℃ and l200℃ showed relatively smaller weight change during oxidation because SiO_2 formed on the SiC-matrix and SiC-fiber sealed the specimen surface before the PyC interface recession by gasification of graphite due to relatively high SiO_2 formation rate. While the PyC-SiC/SiC at 1000℃ showed significant weight loss because the specimen surface was not sealed by SiO_2 and significant PyC interface recession occurred due to relatively slow SiO_2 formation.
机译:为了评估在HCSB覆盖环境下具有常规热解石墨界面(PyC-SiC / SiC)和高级多层界面(ML-SiC / SiC)的SiC / SiC复合材料的氧化行为和机理,采用热重分析(TGA)在He + O_2环境中分别在1000℃和1200℃下进行。在1200℃时PyC-SiC / SiC和1000℃和1200℃时ML-SiC / SiC的重量变化相对较小,这是因为在PyC界面凹陷之前,SiC基体和SiC纤维上形成的SiO_2密封了样品表面。由于较高的SiO_2形成速率,使石墨气化。而在1000℃时PyC-SiC / SiC表现出明显的重量损失,因为样品表面没有被SiO_2密封,并且由于相对较慢的SiO_2形成而导致PyC界面显着凹陷。

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