Synthesis of polymer based catalyst: Optimization and kinetics modeling of the transesterification of Pistacia chinensis oil with diethyl carbonate using acidic ionic liquids

摘要

A novel solid acidic polymeric ionic liquid catalyst was synthesized for ethyl esters production via the esterification of oleic acid with ethanol, normally transesterification of Pistacia chinensis oil with diethyl carbonate. Gas chromatography-mass spectroscopy analysis was used to characterize the products and optimize the reaction conditions to provide P. chinensis oil derived ethyl esters in 93% yield. Kinetic studies performed at different temperatures revealed that the conversion of P. chinensis oil to an ethyl ester follows first order reaction kinetics. The properties of ethyl esters were determined, found to meet the ASTM D6751-02. Results revealed that the catalyst had perfect utility after several runs without much loss in activity. The mild conditions (1:5) P. chinensis oil:diethyl carbonate molar ratio, 300 wt% PIL loading, 120 degrees C, 400 rpm, 6 h, recyclability of the catalyst make the proposed synthesis a sustainable method for the development of ecofriendly, cost-effective biofuels.