Usage of the newly synthesized poly(3-hydroxy butyrate)-b-poly (vinyl benzyl xanthate) block copolymer for vortex-assisted solid-phase microextraction of cobalt (Ⅱ) and nickel (Ⅱ) in canned foodstuffs

摘要

The current research article was reported the synthesis of a novel poly(3-hydroxy butyrate)-b-poly(vinyl benzyl xanthate) block copolymer (PHB-Xa) for vortex-assisted solid-phase microextraction of cobalt(II) and nickel(II) from canned foodstuffs prior to their determinations by flame atomic absorption spectrometry. The block copolymer was synthesized and characterized by nuclear magnetic resonance spectroscopy and Fourier transform infrared spectroscopy. Experimental variables affecting the extraction efficiency of the copolymer were optimized. Since the PHB-Xa block copolymers have a high Tc conjugate structure and hydrophobicity, the use of this adsorbent yielded quantitative results for the extraction of Ni(II) and Co(II). After optimization, the linearities for Ni(II) and Co(II) were 0.05-80 ng mL(-1) and 0.2-100 ng mL(-1), respectively. The limits of detection and the limits of quantification were in the range of 0.015-0.06 ng mL(-1) and 0.05-0.2 ng mL(-1), respectively. The method was successfully applied to determination of Ni(II) and Co(II) in canned foodstuffs prepared by microwave digestion.