Stream Nitrogen Inputs Reflect Groundwater Across a Snowmelt-Dominated Montane to Urban Watershed

摘要

Snowmelt dominates the hydrograph of many temperate montane streams, yet little work has characterized how streamwater sources and nitrogen (N) dynamics vary across wildland to urban land use gradients in these watersheds. Across a third-order catchment in Salt Lake City, Utah, we asked where and when groundwater vs shallow surface water inputs controlled stream discharge and N dynamics. Stream water isotopes (δ~2H and δ~(18)O) reflected a consistent snowmelt water source during baseflow. Near-chemostatic relationships between conservative ions and discharge implied that ground-water dominated discharge year-round across the montane and urban sites, challenging the conceptual emphasis on direct stormwater inputs to urban streams. Stream and groundwater NO_3~- concentrations remained consistently low during snowmelt and baseflow in most montane and urban stream reaches, indicating effective subsurface N retention or denitrification and minimal impact of fertilizer or deposition N sources. Rather, NO_3~- concentrations increased 50-fold following urban groundwater inputs, showing that subsurface flow paths potentially impact nutrient loading more than surficial land use. Isotopic composition of H_2O and NO_3~- suggested that snowmelt-derived urban groundwater intercepted NO_3~- from leaking sewers. Sewer maintenance could potentially mitigate hotspots of stream N inputs at mountain/valley transitions, which have been largely overlooked in semiarid urban ecosystems.