Desorption kinetics of neutral hydrophobic organic compounds from field-contaminated sediment

摘要

The chemical release rates from a field-contaminated sediment (Lake Charles, LA) using Tenax desorption were studied. Two dichlorobenzenes (m-,p-), hexachlorobuiadiene, and hexachlorobenzene were investigated. Contrary to reports that sorption rates are inversely related to K_ow, the slow desorption rates were found to be similar for the four compounds. The data were modeled by a two-compartment irreversible adsorption and radial diffusion model. Desorption kinetics from the first irreversible compartment can be modelea by radial diffusion and assume an irreversible adsorption constant and soil tortuosity of 4.3. The desorption half- life is approximately 2-7 days Desorption from the second irreversible compartment is very slow (half-life of approximately 0.32- 8.62 years)presumably caused by entrapment in soil organic matter that increases the constrictivity of the solid phase to chemical diffusion. From the kinetic data, it is deduced that the diffusion pore diameter of the second irreversible compartment is approxi- mately equal to the critical molecular diameter. The mass of chemicals in this highly constrictive irreversible compartment is approximately one-fourth of the maximum irreversible. Or resistant, compartment. The slow kinetics observed in this study add sdditional support to the notion that the irreversibly sorbed chemicals are ‘ benign’ to the environment.