Evaluation of processes occurring in the bottom nepheloid layer (BNL) of an eastern Mediterranean area using~(234)Th/~(238)U disequilibria

摘要

Particle-reactive radionuclide ~(234)Th and its ratios with the conservative ~(238)U were used to trace the marine processes occurring over short timescales in the bottom nepheloid layer (BNL) of seven stations in the Saronikos Gulf and the Elefsis Bay (Greece) during three seasons (summer 2008, autumn 2008 and winter 2009). Summer was considered as a steady season where low physical processes occur and stratification is well established, autumn as a commutative period and winter as period of extensive trawling and physical activities. The obtained ratio profiles showed excess of ~(234)Th relative to ~(238)U in the BNL of the sampling area during summer, caused by the dissolved fraction of ~(234)Th. During autumn, the situation was different with large ~(234)Th deficit throughout the water column leading to large export fluxes of particles from the water column. Finally, during winter the ratios showed that predominant phenomenon in the area was likely resuspension of bottom sediments. The resuspension signature was additionally evaluated by total suspended matter (TSM) inventories in the BNL. Despite the intense resuspension, small scavenging of dissolved ~(234)Th was recorded in the BNL resulting in high residence times of dissolved ~(234)Th. A 1 order of magnitude difference between dissolved and particu-late ~(234)Th residence times was observed indicating that scavenging from dissolved to particulate ~(234)Th could be highly variable and, as a result, the Saronikos Gulf is a highly dynamic environment, in terms of temporal and spatial particle uptake and removal. Comparing these values to literature ones consistent results were obtained. The possibility of sediment resuspension in the BNL during winter was amplified by the bloom of phytoplankton resulting in even decreased residence times of particulate ~(234)Th (average values). In contrast, the respective residence times of the dissolved fraction of ~(234)Th in the BNL were higher showing a maximum in winter at the stations where resuspension concluded. Nevertheless, ~(234)Th cycling in the area is not controlled by TSM, probably due to the presence of colloids, which could play an essential role in ~(234)Th scavenging.