Magnetic parameters, trace elements, and multivariate statistical studies of river sediments from southeastern India: a case study from the Vellar River

摘要

This contribution constitutes a new study using magnetic parameters and trace element determinations of pollutants in river sediments from the Tamil Nadu state. The Vellar River covers a total length of about 200 km and flows into the Bay of Bengal. Sediment samples were collected at different sediment depths (up to 90 cm) from 12 sites to investigate their magnetic properties (27 samples) and the contents of trace elements (21 out of 27 samples) along the river; as well as to perform magnetic studies for various grain size fractions (16 sub samples). The magnetic results of magnetic susceptibility and remanent magnetizations suggest that the magnetic signal of these sediments is controlled by ferrimagnetic minerals magnetite-like minerals and a minor contribution of antiferromagnetic carriers (such as hematite minerals). Detailed studies of selected samples showed a higher magnetic concentration in finer grain-sized fractions and a slightly different magnetic mineralogy. Magnetic concentration-dependent parameters evidenced high values, which, together with the background values, allowed us to identify magnetic enhancement at some sites. The Pearson correlation and multivariate statistical studies (Principal Component Analysis, Canonical Correlation Analysis) supported the relationship between the magnetic and chemical variables; in particular, magnetic susceptibility, anhysteretic and isothermal remanent magnetization are closely correlated to Co, Cr, Cu, Fe, V, Zn, and the pollution load index. In addition, Principal Coordinate Analysis and fuzzy C-means cluster analysis allowed us to make a classification and to perform a magnetic-chemical characterization of the data into four groups, thereby identifying critical (possibly polluted) sites from the Vellar River.