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Optimization of preparation conditions of sugarcane bagasse activated carbon via microwave-induced KOH activation for stabilized landfill leachate remediation

机译:微波诱导的KOH活化甘蔗渣活性炭制备条件的稳定化渗滤液修复

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摘要

Adsorption via activated carbon has been testified as an effective way for removing high molecular weight refractory organic compounds from old landfill leachate which is hard to be treated biologically. The present work reveals the preparation and optimization of sugarcane bagasse-based activated carbon (SCAC) by microwave-induced KOH activation for the adsorptive treatment of organic and inorganic contaminants from the mature anaerobic landfill leachate using response surface methodology technique. The effects of variable parameters in SCAC preparation including activation power, activation time and KOH impregnation were studied. Based on the central composite design, the quadratic model was employed in order to correlate the effect of variable parameters in SCAC preparation on adsorptive removal of pollutants. The achieved removal efficiencies of color, COD and ammonia were 97.83, 88.14 and 47.25 %, based on optimum conditions of SCAC at 550 W of activation power, 7 min of activation time and 1.55 of impregnation ratios. The experimental results showed the capability of SCAC prepared via microwave-induced KOH activation in the treatment of stabilized landfill leachate.
机译:已经证明,通过活性炭吸附是从旧的垃圾填埋场渗滤液中去除高分子量难熔有机化合物的有效方法,而垃圾渗滤液很难进行生物学处理。本工作揭示了通过响应面方法技术通过微波诱导的KOH活化来制备和优化甘蔗渣的活性炭(SCAC),用于吸附处理来自成熟厌氧垃圾渗滤液的有机和无机污染物。研究了SCAC制备中各种参数的影响,包括活化能力,活化时间和KOH浸渍。基于中央复合设计,采用二次模型以关联SCAC制备中的可变参数对污染物的吸附去除的影响。基于SCAC在550 W活化功率,7分钟活化时间和1.55浸渍比下的最佳条件,基于色氨酸,COD和氨的去除效率分别为97.83、88.14和47.25%。实验结果表明,通过微波诱导的KOH活化制备的SCAC能够处理稳定的垃圾渗滤液。

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