Adsorption and desorption of iodine by various Chinese soils I. Iodate

摘要

In order to assess the adsorption of iodate by different soils from China, a series of batch experiments were conducted. It was found that soils rich in iron oxide had high affinity for iodate. lodate adsorption isotherms could be well fitted with both Langmuir and Freundlich equations. lodate adsorption by 20 different soils from China revealed that iodate adsorption was significantly correlated with soil organic matter negatively and positively with free iron oxide contents. At initial concentration of 4 mg I L~(-1), iodate adsorption ranged between 9 and 34 mg kg~(-1)' soil. No correlation between iodate adsorption and cation exchange capacity and soil pH was found. For a single soil, there was a significant linear relationship between the amounts of iodate adsorbed and desorbed, but for a group of different soils, the relationship between the amounts of iodate adsorption and desorption followed a nonlinear relationship, the deviation mainly occurred at high adsorption side. The relationship between K_d and free aluminum oxide and free iron oxide contents showed an exponential relationship for various soils with exception of the soil from Hetian in Xinjiang.