Effect of electron transport layer engineering based on blue phosphorescent organic light-emitting diodes

摘要

A main requirement for achieving high efficiency in organic light-emitting diodes (OLEDs) is that all charges and electrically generated excitons should be employed for emission. We fabricated blue phosphorescent OLEDs with four types electron transporting layers, which were doped with lithium quinolate (Liq) from 0% to 10%. A series of blue devices consisted of indium tin oxide (ITO, 180nm)/4,4-bis[N-(naphthyl)-N-phenyl-amino]biphenyl (NPB, 50nm)/N,N'-dicarbazolyl-3,5-benzene (mCP, 10nm)/irid-ium(Ⅲ)bis[(4,6-di-fluoropheny)-pyridinato-N,C~2] picolinate (FIrpic) doped in mCP (8%, 30nm)/l,3,5-tris(N-phenylbenzimidazole-2-yl)benzene (TPBi, 20 nm)/TPBi mixed with Liq (20 nm)/Liq (2 nm)/alumi-num (Al, 100 nm). The blue OLED doped with 5% Liq, which demonstrated a maximum luminous efficiency and external quantum efficiency of 17.64 cd/A and 8.78%, respectively, were found to be superior to the other blue devices.