Structural, photocatalytic and electrochemical studies on facile combustion synthesized low-cost nano chromium (III) doped polycrystalline magnesium aluminate spinels

摘要

An economic low-temperature self-ignition solution combustion method was used to synthesize 1-11 mol% chromium ion (Cr3+) doped MgAl2O4 nanoparticles (NPs). The structural, morphological and energy gap variations due to the influence of Cr3+ on the host matrix were evidenced by powder X-ray diffraction (PXRD), Fourier transformed infrared spectroscopy (FTIR), diffuse reflectance spectroscopy (DRS), and transmission electron microscopy (TEM). Under visible light irradiation, the as-prepared NPs showed excellent photocatalytic activities (PCA) for the industrial dye Acid Red-88 (AR-88) and pyrocatechol (PY) - an emerging pollutant (EP). The experiments were carried out at room temperature in an aqueous solution at a concentration of 20 ppm. Among others, MgAl2O4:Cr3+(5 mol%) showed 91.38% degradation within 150 min exhibiting zero-order kinetics and 82% degradation in 6 h displaying the first order kinetics for AR-88 dye and PY EP, respectively. In this case, a greater number of hydroxyl (OH.) radicles dominate over other reactive oxygen species (ROS), such as holes and singlet oxygens (1O2) under different pH conditions. Electrochemical studies have yielded the proton diffusion coefficient (D) value as large as 2.145 × 10-4 cm2s-1 for the optimized NP electrode, which is substantially greater than 1.0935 × 10-5 cm2s-1 for the pure MgAl2O4 one owing to the intercalated anions and structurally disordered density of the electrode material. This superior electrochemical behaviour suggests the potential application of the optimized NP material as an anodic electrode for supercapacitors.