Laboratory study of the collection efficiency of submicron aerosol particles by cloud droplets – Part II: Influence of electric charges

摘要

A new In-Cloud Aerosol Scavenging Experiment (In-CASE) has been developed to measure the collection efficiency (CE) of submicron aerosol particles by cloud droplets. Droplets fall at their terminal velocity through a 1?m high chamber in a laminar flow containing aerosol particles. At the bottom of the In-CASE chamber, the droplet train is separated from the aerosol particles flow, and the droplets are collected in an impaction cup, whereas aerosol particles are deposited on a high-efficiency particulate air?(HEPA) filter. The collected droplets and the filter are then analysed by fluorescence spectrometry since the aerosol particles are atomised from a sodium fluorescein salt solution ( C 20 H 10 Na 2 O 5 ). In-CASE fully controls all the parameters which affect the CE – the droplets and aerosol particles size distributions are monodispersed, the electric charges of droplets and aerosol particles are known and set, and the relative humidity is indirectly controlled via the chamber's temperature. This paper details the In-CASE setup and the dataset of 70 measurements obtained to study the impact of the electric charges on CE. For this purpose, droplets and particles charges are controlled through two charging systems developed in this work – both chargers are detailed below. The droplet charge varies from - 3.0 × 10 4 ± 1.4 × 10 3 to + 9.6 × 10 4 ± 4.3 × 10 3 elementary charges, while the particle charge ranges from zero to - 90 ± 9 elementary charges depending on the particle radius. A droplet radius of 48.5±1.1 ? μ m has been considered for four particle dry radii between 100 and 250 nm while the relative humidity level during experiments is 95.1±0.2 ?%. The measurements are then compared to theoretical models from literature – showing good agreement.