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Effect of growth conditions on the mechanical properties of lanthanum-gallium tantalate crystals

机译:生长条件对镧 - 镓钽酸盐晶体力学性能的影响

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The effect of growth conditions, anisotropy and polarity of specimens on the mechanical properties of lanthanum-gallium tantalate La3 Ta0.5Ga5.5O14 single crystals grown in different atmospheres (argon (Ar), argon with oxygen addition (Ar+(<2%)O2 and Ar+(2%)O2 ) and air) was studied. The test specimens for the measurements were cut perpendicularly to a 3rd order axis (Z cuts) and in polar directions perpendicular to a 2nd order axis (Y cuts). The polarity of the Y cut specimens was tested by piezoelectric response. The brittleness was evaluated by microindentation at 3, 5, 10 and 25 g loads. The brittleness proved to show itself at a 5 g and the higher loads regardless of growth atmosphere. Therefore microhardness tests were done at loads of within 3 g. The microhardness HV of the specimens was measured with an DM 8B Affri microhardness tester by Vickers methods. The hardness H, elastic modulus E and elastic recovery coefficient R were measured with a Berkovich pyramid on a CSM Nano-Hardness Tester using the instrumented indentation (nanoindentation) method. Growth atmosphere was shown to affect the mechanical properties of lanthanum-gallium tantalate crystals: crystals grown in an oxygen-free argon atmosphere had the lowest microhardness, hardness, elastic modulus and elastic recovery coefficient. The lowest microhardness was detected in Z cut specimens regardless of growth atmosphere. The mechanical properties of polar Y cuts proved to be anisotropic: the microhardness, hardness, elastic modulus and elastic recovery coefficient of these cuts were lower for positive cuts than for negative ones regardless of growth atmosphere. Y and Z cut langatate specimens grown in argon with less than two percent oxygen exhibited strong elastic modulus and elastic recovery coefficient anisotropy.
机译:在不同大气中生长的镧 - 镓La3 Ta0.5ga5.5014单晶的机械性能对不同大气生长的单晶(氩气(Ar +(ar +(<2%)O2的氩气(Ar +(<2%)O 2的氩气研究了Ar +(2%)O2)和空气)。测量的测试样本垂直于第三阶轴(Z切口)和垂直于第二阶轴线(Y切割)的极性方向切割。通过压电响应测试Y切割样本的极性。通过3,5,10和25g负载的微观凸起评估脆性。无论生长气氛如何,脆性都证明了令人叹息的5克和较高的负载。因此,在3g内的载荷下进行显微硬度测试。用Vickers方法用DM 8B亚胺微硬度测试仪测量样品的显微硬度HV。使用仪表压痕(纳米凸缘)法用Berkovich金字塔用Berkovich金字塔测量硬度H,弹性模量E和弹性回收系数R.出现生长气氛会影响镧 - 镓钽酸盐晶体的力学性能:在无氧氩气氛中生长的晶体具有最低的微硬度,硬度,弹性模量和弹性回收系数。无论生长气氛如何,在Z切割试样中检测到最低显微硬度。 Polar y切口的机械性能证明是各向异性的:对于阳性切割而不是对于生长气氛而言,这些切口的微硬度,硬度,弹性模量和弹性回收系数较低。 Y和Z切割植物在氩气中生长,氧气小于氧气少于含量强烈的弹性模量和弹性回收系数各向异性。

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