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Modification Mechanism of Asphalt Modified with Rock Asphalt and Styrene-Butadiene Rubber (SBR)

机译:用岩沥青和苯乙烯 - 丁二烯橡胶改性沥青改性机制(SBR)

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High-performance asphalt binder plays an important role in the durable asphalt pavement. Asphalt modified by rock asphalt (RA) is one of the high-performance modified asphalt materials. It was used in road engineering as a relatively environmentally friendly material, because rock asphalt takes some advantages of large reserves, easy treatment, and efficient modification. Moreover, the main component of rock asphalt is bitumen, which enables it to substitute part of the binder used in asphalt mixtures. On the other hand, the negative low-temperature performance of RA modified asphalt impeded its application in cold regions. The object of this paper is to improve the low-temperature performance of RA modified asphalt by compound modified with styrene-butadiene rubber (SBR). The 70-penetration grade binder and the RA modified asphalt with 15% RA by weight were applied as the base binder. Five types of RA-SBR modified asphalt were prepared, and the content of SBR was 2%, 4%, 5%, 6% and 8% by weight of BRA modified binder. The Fourier transform infrared spectroscopy (FTIR) tests were utilized to illustrate the reasons for the poor low-temperature performance of BRA modified asphalt and reveal the compound modification mechanism of BRA-SBR modified asphalt. The Brookfield viscosity test, dynamic shear rheometer test, and bending beam rheometer test were adopted to reveal the variation patterns of rheological behavior and low-temperature performance with mass contents of SBR. The test results indicated that the worse of low-temperature performance was caused by the increase of asphaltene content and the stress concentration due to ash in RA modified asphalt. And the compound modification is a physical process. The addition of SBR has improved the low-temperature performance of RA modified asphalt dramatically. And based on the rheological behaviors and low-temperature performance of RA-SBR compound modified asphalt, the optimum content of SBR was determined, which is about 4%~5%.
机译:高性能沥青粘合剂在耐用的沥青路面中起着重要作用。由岩石沥青(RA)改性的沥青是一种高性能改性沥青材料之一。它被用作道路工程作为相对环保的材料,因为岩石沥青占储量,易于治疗和高效修改。此外,岩石沥青的主要成分是沥青,使其能够替代沥青混合物中使用的粘合剂的部分。另一方面,Ra改性沥青的负低温性能阻碍了其在寒地区域的应用。本文的目的是通过用苯乙烯 - 丁二烯橡胶(SBR)改性的化合物改善Ra改性沥青的低温性能。将70渗透级粘合剂和RA改性沥青与15%Ra重量重量作为碱粘合剂施加。制备五种类型的RA-SBR改性沥青,SBR的含量为2%,4%,5%,6%和8重量%的BRA改性粘合剂。傅里叶变换红外光谱(FTIR)试验用于说明BRA改性沥青低温性能差的原因,并揭示了BRA-SBR改性沥青的复合改性机理。采用Brookfield粘度试验,动态剪切流变仪测试和弯曲光束流变仪测试,揭示了SBR质量含量的流变行为和低温性能的变化模式。测试结果表明,低温性能的较差是由沥青质含量的增加和Ra改性沥青中灰分引起的应力集中引起的。并且复合改性是物理过程。添加SBR的增加改善了RA改性沥青的低温性能。基于RA-SBR化合物改性沥青的流变行为和低温性能,测定SBR的最佳含量,为约4%〜5%。

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