Formation of Polymer Walls through the Phase Separation of a Liquid Crystal Mixture Induced by a Spatial Elastic Energy Difference

摘要

We propose a method to form polymer walls without the use of a photomask in a liquid crystal (LC) cell by phase separation of an LC mixture induced by a spatial elastic energy difference. When an in-plane electric field is applied to a vertically aligned cell filled with a mixture of LC and a reactive monomer (RM), a high spatial elastic energy is induced along the direction perpendicular to the interdigitated electrodes. RMs move to the boundaries where the elastic energy is very high and an in-plane component of the applied electric field exists, which results in the phase separation of the LC/RM mixture. We have shown that we can form polymer walls by applying ultraviolet light irradiation to the LC cell. These polymer walls can function as alignment layers. We observed morphological patterns of the polymer structure through polarized optical microscopy, scanning electron microscopy, and atomic force microscopy. The polymer walls formed in an LC cell can affect the orientation of LCs in the lateral direction. Bistable switching of a polymer-walled cell could be achieved by using three-terminal electrodes where both vertical and in-plane electric fields can be applied. Vertical anchoring with the alignment layer on each substrate allows LC molecules to remain vertically aligned after removal of the applied vertical electric field. Furthermore, in-plane anchoring with the formed polymer walls allows the LC molecules to remain homogeneously aligned after removal of the applied in-plane electric field. The proposed method for the formation of polymer structures could be a useful tool to fabricate LC cells for various applications. As a bistable phase-grating device, the diffraction efficiency of a polymer-walled cell was comparable to that of a pure-LC cell. Its operating voltage was 44% lower than that of a pure-LC cell owing to in-plane anchoring provided by the polymer walls. Moreover, it can be operated with very low power because it does not require power to maintain the state. In addition, the total response time of a polymer-walled cell was approximately 68% shorter than that of a pure-LC cell because all switching was forcibly controlled by applying an electric field.