A nanoscale Fe(ii) metal–organic framework with a bipyridinedicarboxylate ligand as a high performance heterogeneous Fenton catalyst

摘要

With 2,2′-bipyridine-5,5′-dicarboxylate as the ligand, a nanoscale Fe( II ) MOF material (Fe-bpydc) was synthesized. Fe-bpydc could activate H _(2) O _(2) to degrade organic pollutants in near neutral conditions, and its activity and stability are superior to reported results. Interestingly, Fe-bpydc only consumes H _(2) O _(2) in the presence of organics, leading to high H _(2) O _(2) utilization efficiency.