An urchin-like Ni3ZnC0.7–carbon nanotube-porous carbon composite derived from metal–organic gel as a cathode material for rechargeable Li–O2 batteries

摘要

An urchin-like Ni _(3) ZnC _(0.7) –carbon nanotube-porous carbon composite was synthesized, for the first time, by one-step direct thermolysis of a metal–organic gel in a conventional horizontal tube furnace without using any additional carrier gas or catalyst. The urchin-like particles of the obtained composite with a particle size of ～2 μm exhibit a sphere-like core, and CNTs grow outward from the core. And the Ni _(3) ZnC _(0.7) nano-particles are embedded in the composite, including at the end of the nanotubes. When used as the cathode material of Li–O _(2) batteries, the composite exhibits excellent electrochemical performances, delivering a good cycle performance and having a discharge capacity of ～7390 mA h g ~(?1) _(carbon+catalyst) at 0.1 mA cm ~(?2) .