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Etherification to improve the performance of lignosulfonate as dye dispersant

机译:以提高木质素磺酸盐作为染料分散剂的性能的醚化

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摘要

Lignosulfonates (SLs) are widely used as dye dispersants. However, they have some disadvantages, including poor high temperature dispersibility and severe fiber staining resulting from the abundant phenolic hydroxyl content in the SL molecules. In this work, etherified lignosulfonates (ESLs) were obtained by using epichlorohydrin to reduce the content of phenolic hydroxyl while increasing the molecular weight. ESLs with lighter color can reduce fiber staining rate by 52% due to whitening by the epichlorohydrin process. The lower adsorption capacity of ESLs onto the surface of fibers can reduce the fiber staining effect, owing to the lower phenolic hydroxyl content. The ESLs also exhibit superior high temperature stability to SL because of their higher adsorption capacity and more rigid adsorption films.
机译:木质素磺酸盐(SLS)广泛用作染料分散剂。然而,它们具有一些缺点,包括由SL分子中的丰富的酚羟基含量产生的差的高温分散性和严重的纤维染色。在这项工作中,通过使用表氯醇获得醚化的木质素磺酸盐(ESLS),以减少酚羟基的含量,同时增加分子量。由于表氯醇过程的美白,具有较浅颜色的ESL可以将纤维染色率降低52%。由于酚羟基含量较低,ESLS在纤维表面上的吸附能力降低,可以降低纤维染色效果。由于其吸附能力和更刚性的吸附膜,ESLS也表现出优异的高温稳定性。

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