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One-step ultra-rapid fabrication and thermoelectric properties of Cu2Se bulk thermoelectric material

机译:Cu2SE批量热电材料的一步式超快速制造和热电性能

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摘要

Cu _(2) Se is a promising material for high temperature thermoelectric energy conversion due to its unique combination of excellent electronic properties and low thermal conductivity owing to its ionic liquid characteristics at high temperature. In this paper, fully dense single-phase bulk Cu _(2) Se material was prepared by the combination of self-propagating high-temperature synthesis (SHS) with in situ quick pressing (QP) for the first time. This new approach shortens the duration of the synthesis from days to hours compared to conventional preparation methods. SHS-QP technique is an ultra-fast preparation method, which utilizes the heat released by the SHS reaction and an external applied pressure to achieve the synthesis and densification of materials in one-step. The ultra-fast process of the SHS-QP technique enables the fabrication of single-phase Cu _(2) Se bulk materials with relative density of over 98% and with precise control over the stoichiometry owing to the ability to suppress the Se vapor during the reaction. The SHS-QP prepared Cu _(2) Se samples exhibit excellent thermoelectric figure of merit, ZT ~ 1.5 at 900 K, which is comparable to those of Cu _(2) Se materials prepared by conventional methods. This study opens a new avenue for the ultra-fast and low-cost fabrication of Cu _(2) Se thermoelectric materials.
机译:Cu _(2)SE是高温热电能转换的有希望的材料,由于其在高温下的离子液体特性优异的电子性能和低导热率的独特组合,因此由于其离子液体特性而具有优异的电子性能和低导热率。在本文中,通过将自展示的高温合成(SHS)的组合首次使用自我繁殖的高温合成(SHS)的组合来制备完全致密的单相体积Cu _(2)SE材料。与常规制备方法相比,这种新方法从天到时间缩短了合成的持续时间。 SHS-QP技术是一种超快速制备方法,其利用SHS反应释放的热量和外部施加压力,以在一步中实现材料的合成和致密化。 SHS-QP技术的超快速过程使得具有相对密度的单相Cu _(2)Se散装材料以超过98%的相对密度,并且由于抑制SE蒸汽的能力而在化学计量中进行精确控制反应。 SHS-QP制备的Cu _(2)Se样品表现出优异的热电图,Zt〜1.5在900 k下,其与常规方法制备的Cu _(2)Se材料相当。本研究开辟了Cu _(2)SE热电材料的超快速和低成本制造的新途径。

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