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2N+4-rule and an atlas of bulk optical resonances of zigzag graphene nanoribbons

机译:Zigzag Graphene Nanoribbons的散装光学共振的2N + 4规则和图案

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Development of on-chip integrated carbon-based optoelectronic nanocircuits requires fast and non-invasive structural characterization of their building blocks. Recent advances in synthesis of single wall carbon nanotubes and graphene nanoribbons allow for their use as atomically precise building blocks. However, while cataloged experimental data are available for the structural characterization of carbon nanotubes, such an?atlas is absent for graphene nanoribbons. Here we theoretically investigate the optical absorption resonances of armchair carbon nanotubes and zigzag graphene nanoribbons continuously spanning the tube (ribbon) transverse sizes from 0.5(0.4) nm to 8.1(12.8) nm. We show that the linear mapping is guaranteed between the tube and ribbon bulk resonance when the number of atoms in the tube unit cell is [Formula: see text], where [Formula: see text] is the number of atoms in the ribbon unit cell. Thus, an atlas of carbon nanotubes optical transitions can be mapped to an atlas of zigzag graphene nanoribbons.
机译:片上集成的碳基光电纳米电路的开发需要其构建块的快速和非侵入性结构特征。单壁碳纳米管和石墨烯纳米纤维合成的最新进展允许其用作原子精确构建块。然而,虽然编目的实验数据可用于碳纳米管的结构表征,但是石墨烯纳米队不存在这种αAtlas。在这里,我们从理论上研究了扶手椅碳纳米管和锯齿形石墨烯纳米的光学吸收谐振,连续地跨越0.5(0.4)Nm至8.1(12.8)nm的管(带)横向尺寸。当管单元单元中的原子数[公式:参见文本]时,管和带子体积谐振之间保证线性映射是保证的,其中[公式:参见文本]是带单元电池中的原子数。因此,碳纳米管光学转变的图谱可以映射到Z字形石墨烯纳米波动的地图。

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