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Green light powered molecular state motor enabling eight-shaped unidirectional rotation

机译:绿色光源分子态电机,可实现八种单向旋转

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Molecular motors convert external energy into directional motions at the nano-scales. To date unidirectional circular rotations and linear motions have been realized but more complex directional trajectories remain unexplored on the molecular level. In this work we present a molecular motor powered by green light allowing to produce an eight-shaped geometry change during its unidirectional rotation around the central molecular axis. Motor motion proceeds in four different steps, which alternate between light powered double bond isomerizations and thermal hula-twist isomerizations. The result is a fixed sequence of populating four different isomers in a fully unidirectional trajectory possessing one crossing point. This motor system opens up unexplored avenues for the construction and mechanisms of molecular machines and will therefore not only significantly expand the toolbox of responsive molecular devices but also enable very different applications in the field of miniaturized technology than currently possible.
机译:分子电机将外部能量转化为纳米尺度的方向运动。迄今为止单向圆形旋转和线性运动已经实现,但在分子水平上仍然未探测更复杂的方向轨迹。在这项工作中,我们呈现由绿光供电的分子电机,允许在中央分子轴周围的单向旋转期间产生八种几何变化。电动机运动以四个不同的步骤进行,在光源双键异构化和热呼啦圈扭曲异构化之间交替。结果是在具有一个交叉点的完全单向轨迹中填充四种不同异构体的固定序列。该电机系统开辟了未开发的途径,用于分子机械的构造和机制,因此不仅可以显着扩展响应分子装置的工具箱,而且还可以在小型化技术领域实现比目前可能的宽度的工具箱。

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