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Adsorption of Naphthalene on Modified Zeolite from Aqueous Solution

机译:萘对水溶液改性沸石的吸附

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In this study, the modified zeolite with certain hydrophobicity was prepared by modifying natural zeolite by the silane coupling agents such as vinyltrimethoxysilane (VTMO), trimethoxysilane (TMS) and trimethylchlorosilane (TMCS). The modified zeolite has a higher hydrophobicity and adsorption capacity than natural zeolite while ensuring the advantages of natural zeolite, which is more conducive to the adsorption of organic pollutants from aqueous solution. The adsorption experiment on naphthalene in aqueous solution shows that the modified zeolite has a stronger adsorption capacity. In the adsorption thermodynamics experiment, the isothermal adsorption models such as Freundlich and Langmuir can better describe the adsorption of naphthalene on modified zeolite, but the isothermal adsorption model Freundlich has a higher correlation. At 303K, the static adsorption capacity is 339μg/g. The kinetic analysis shows that the adsorption of naphthalene on modified zeolite conforms to the quasi-second order kinetic model.
机译:在本研究中,通过通过硅烷偶联剂如乙烯基三甲氧基硅烷(VTMO),三甲氧基硅烷(TMS)和三甲基氯硅烷(TMC)来改变天然沸石来制备具有某些疏水性的改性沸石。改性沸石具有比天然沸石更高的疏水性和吸附能力,同时确保天然沸石的优点,这更有利于从水溶液中吸附有机污染物。水溶液中萘的吸附试验表明,改性沸石具有较强的吸附能力。在吸附热力学实验中,诸如Freundlich和Langmuir等等温吸附模型可以更好地描述萘对改性沸石的吸附,但等温吸附模型Freundlich具有更高的相关性。在303K时,静态吸附容量为339μg/ g。动力学分析表明,萘对改性沸石的吸附符合准二阶动力学模型。

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