Synthesis and effect of substituent position, metal type on the electrochemical properties of (3-morpholin-4-ylpropoxy) groups substituted cobalt, manganese phthalocyanines

摘要

In this work, 4-(3-morpholin-4-ylpropoxy)phthalonitrile 2 , 3-(3-morpholin-4-ylpropoxy)phthalonitrile 3 , Co(II)Pc and Mn(III)Pcs containing (3-morpholin-4-ylpropoxy) groups at peripheral and nonperipheral positions were synthesized. Phthalonitrile derivatives (2 and 3 ), Co(II)Pc and Mn(III)Pcs (2a, 2b, 3a, 3b ) were characterized by using FT-IR, NMR (only for 2 and 3 ), mass and UV-Vis (except 2 and 3 ) spectral data techniques. Also, electrochemistry of (3-morpholin-4-ylpropoxy) group substituted Co(II)Pc and Mn(III)Pcs were inspected by using cyclic voltammetry. Electrochemical studies show that (3-morpholin-4-ylpropoxy) group substituted Co(II)Pc and Mn(III)Pcs electropolymerized on the Pt working electrode.