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Massive generation of metastable bulk nanobubbles in water by external electric fields

机译:外部电场在水中大量产生亚料散装纳米杆菌

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摘要

Nanobubbles (NBs) are nanoscopic gaseous domains than can exist on solid surfaces or in bulk liquids. They have attracted substantial attention due to their long-time (meta)stability and a high potential for real-world applications. Using an approach not previously investigated, we exploit surface-electrostatic NB formation and stabilization via application of external electric fields in gas-liquid systems, with the marked result of massively increased gas uptake into the liquid in NB form. The de facto gas solubility enhancement (over many months) ranges from 2.5-fold for oxygen to 30-fold for methane vis-à-vis respective Henry’s law values for gas solubility; the more hydrophobic the gas, the more spectacular the increase. Molecular dynamics simulations reveal that the origin of NBs’ movement lies in dielectrophoresis, while substantial NB stabilization arises from a surface-polarization interaction.
机译:纳米泡(NBS)是纳米镜的气态域,而不是在固体表面上存在或散装液体。由于它们的长期(META)稳定性和现实世界应用的高潜力,它们引起了大量的关注。使用先前研究的方法,我们通过在气液系统中施加外部电场来利用表面静电Nb形成和稳定性,具有大规模增加的气体吸收到Nb形式中的液体的显着结果。事实上的气体溶解度增强(超过几个月)从2.5倍的氧气范围为30倍,用于甲烷Vis-in-Vis的气体溶解度的亨利法律值;气体疏水越疏水,增加越壮观。分子动力学模拟表明,NBS运动的起源在于介电电泳,而基本的Nb稳定从表面极化相互作用产生。

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