Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles

Aksenov Nicolai A.; Aksenov Alexander V.; Ovcharov Sergei N.; Aksenov Dmitrii A.; Rubin Michael

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Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles

机译：在与碳基亲核试剂的反应中电泳活化的硝基烷烃

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Unusual reactivity of nitroalkanes, involving formation of aci-forms (nitronic acids or nitronates) and their subsequent interaction with carbon-based nucleophiles, is surveyed in this review.

机译：在本次审查中，调查了Nitroalkanes的不寻常的反应，涉及形成ACI - 形式（硝酸盐或亚硝酸盐）及其随后的与碳亲核试剂的相互作用。

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《Frontiers in Chemistry》 |2020年第1期|共13页
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Aksenov Nicolai A.; Aksenov Alexander V.; Ovcharov Sergei N.; Aksenov Dmitrii A.; Rubin Michael;
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nitroalkanesElectrophilic attacksynthetic methodologyC-H functionalizationOximes;

机译：Nitroalkanes电泳攻击合成方法C-H官能化毒性;

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1. Difluoro-λ~3-Bromane-lnduced Oxidative Carbon-Carbon Bond-Forming Reactions: Ethanol as an Electrophilic Partner and Alkynes as Nucleophiles [J] . Masahito Ochiai, Akira Yoshimura, Takeshi Mori, Journal of the American Chemical Society . 2008,第12期

机译：二氟-λ〜3-溴诱导的氧化碳-碳键形成反应：乙醇作为亲电子分子，炔烃作为亲核试剂
2. Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines [J] . RSC Advances . 2019,第67期

机译：在向咪唑啉的途径中，在与脂族二胺反应中电泳活化的硝基烷烃
3. Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines [J] . Alexander V. Aksenov, Nicolai A. Aksenov, Nikolai A. Arutiunov, RSC Advances . 2019,第67期

机译：在向咪唑啉的途径中，在与脂族二胺反应中电泳活化的硝基烷烃
4. "Cation Pool" Method. Generation and Accumulation of Carbocations by Low Temperature Electrolysis and Their Reactions with Carbon Nucleophiles [C] . Jun-ichi Yoshida, Seiji Suga, Shinkichi Suzuki The Meeting of the Electrochemical Society . 2001

机译：“阳离子池”方法。低温电解的生成和积累碳酸碳和碳亲核试剂的反应
5. Organometallic Enantiomeric Scaffolds in the Synthesis of Alkaloids: I. Homo-SN2'-like Reaction/Annulative Demetallation and the Application in the Synthesis of (+)-Isofebrifugine II. Uncatalyzed Electrophilic Carbon-Carbon Bond Forming Reactions of Pyranyl and Pyridinyl Molybdenum Complexes. [D] . Chen, Wenyong. 2010

机译：生物金属对映体支架在生物碱的合成中：I.同源-SN2'-样反应/环形脱金属化及其在合成（+）-异氟乙啶中的应用II。吡喃基和吡啶基钼络合物的未催化亲电碳-碳键形成反应。
6. Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles [O] . Nicolai A. Aksenov, Alexander V. Aksenov, Sergei N. Ovcharov, 2020

机译：与碳基亲核试剂反应的亲电子活化的硝基烷
7. Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles [O] . Nicolai A. Aksenov, Alexander V. Aksenov, Sergei N. Ovcharov, 2020

机译：在与碳基亲核试剂的反应中电泳活化的硝基烷烃

Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles

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