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2-[1-(4-tert-Butyl-phen-yl)-4,5-diphenyl-1H-imid-azol-2-yl]-4,6-di-chloro-phenol

机译:2- [1-(4-叔丁基 - phen-y1)-4,5-二苯基-1H-咪硅-Azol-2-y1] -4,6-二氯 - 苯酚

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摘要

In the title compound, C 31 H 26 Cl 2 N 2 O, the 4,6-di-chloro-phenol and the imidazole rings are almost coplanar, with a dihedral angle of 8.89?(6)° between them and an intra-molecular O—H?N hydrogen bond occurs between the rings. The dihedral angles subtended by the tert -butyl-phenyl ring and the two phenyl rings with the imidazole ring are 85.18?(9), 81.22?(9) and 19.00?(8)°, respectively. The methyl groups of the tert -butyl grouping are disordered over two sets of sites in 0.589?(5):0.411?(5) ratio. In the crystal, inversion dimers linked by pairs of weak C—H?Cl inter-actions generate R 2 2 (24) loops.
机译:在标题化合物中,C 31h 26 Cl 2 N 2 O,4,6-二氯 - 苯酚和咪唑环几乎是共面,其中二向角度为8.89?(6)°和内部分子O-H 2氢键在环之间发生。由叔丁基 - 苯基环和与咪唑环的两种苯基环赋予的二面角是85.18?(9),81.22?(9)和19.00?(8)°。叔丁基的甲基在0.589中的两组位点上紊乱,在0.589?(5):0.411?(5)的比例上。在晶体中,通过弱C-H对连接的反演二聚体连接。CL互动产生R 2 2(24)环。

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