[2,2′-Bis(di-phenyl-phosphan-yl)-1,1′-binaphthyl-κ2P,P′]di-chlorido-platinum(II) acetonitrile trisolvate

摘要

The crystal structure (150?K) of the racemic title compound, [PtCl 2 (C 44 H 32 P 2 )]·3CH 3 CN, has been determined. The asymmetric unit comprises a single mol-ecule of the title compound co-crystallized with three aceto-nitrile solvent mol-ecules. Four mol-ecules are observed in the unit cell, with R and S enanti-omers present in a 2:2 ratio. Evidence of intra-molecular π -stacking is observed with no discernable inter-molecular inter-actions.