(Bi-phenyl-2,2′-di-yl)[1,3-bis--(di-phenyl-phosphan-yl)propane-κ2P,P′]platinum(II)

摘要

The C2P2?donor set in the title compound, [Pt(C12H8)(C27H26P2)], defines a distorted planar coordination environment about the PtII?atom with small deviations from planarity. The bidentate nature of the biphenyl dianionic ligand results in a C—Pt—C bond angle of 79.94?(16)° and a P—Pt—P bond angle of 93.40?(4)°. The average Pt—C bond length is 2.083?(3)?? [range 2.081?(4)–2.085?(4)??]; the average Pt—P bond length is 2.308?(8)?? [range 2.3030?(11)–2.3136?(11)??].