trans-Di-chlorido-{3,4-dimeth-oxy-2-[(2,3-η)-prop-2-en-1-yl]benzene}(pyridine-κN)platinum(II)

摘要

In the title organoplatinum(II) complex, [PtCl 2 (C 5 H 5 N)(C 11 H 14 O 2 )], the methyl-eugenol ligand only coordinates to the Pt II atom through the ethyl-enic double bond. The coordination is completed by the N atom of the pyridine ligand and two Cl atoms positioned trans with respect to each other. The pyridine and benzene rings are inclined to one another by 68.6?(2)°. In the crystal, mol-ecules are linked via a number of C—H?Cl and C—H?O hydrogen bonds, forming sheets parallel to the bc plane.