首页> 外文期刊>IUCrData >catena-Poly[[[(acetato-κ2O,O′)aqua-cadmium(II)]-μ-l-threoninato-κ3N,O:O′] monohydrate]
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catena-Poly[[[(acetato-κ2O,O′)aqua-cadmium(II)]-μ-l-threoninato-κ3N,O:O′] monohydrate]

机译:Catena-Poly [[(乙酰-K2O,O')Aqua-镉(II)] - M-L-苏氨酸-K3N,O:O'单水合物]

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摘要

The title compound, {[Cd(C 2 H 3 O 2 )(C 4 H 8 NO 3 )(H 2 O)]·H 2 O} n , was synthesized from the reaction between L -threonine and cadmium acetate dihydrate. The complex consists of the Cd II metal ion bonded to bidentate threonine and acetate anions, and one water mol-ecule. The carboxyl-ate group of L -threonine bridges two metal cations related by the crystallographic screw axis parallel to [010], to form a one-dimensional polymeric structure in the crystal. The asymmetric unit is completed by one lattice water mol-ecule, which is involved in hydrogen bonds.
机译:从L-Threonine和乙酸镉二水合物之间的反应合成标题化合物,{[Cd(C 2 H 3 O 2)(C 4 H 8 NO 3)(H 2 O)]·H 2 O} N。该综合体由CDI II金属离子与二硫胺和乙酸盐阴离子粘合,以及一种水摩尔肉体。 L-Threonine的羧基 - ATE组桥接两个由平行于[010]的晶体螺旋轴相关的金属阳离子,以在晶体中形成一维聚合物结构。不对称单元由一个晶格水摩尔 - eCule完成,其参与氢键。

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