Electro-catalytic Reduction of Aqueous Nitrates using Cu-Sn and Cu-Pd Cathodes

摘要

Water treatment systems are used globally to reduce environmental impacts or to provide potable water,thus fulfilling established water quality standards. Electrocatalytic nitrate removal is a promising tool toaddress upcoming problems related to nitrate contamination. This study compares the employment of alow cost CuSn6 based catalyst with a noble metal Cu - Pd catalyst in a laboratory and a continuouslyoperating pilot apparatus to treat nitrate contaminated water from a well. In contrast with commonapplications, a saturated carbonic acid was used as the anolyte solution, which stabilized the pH in theanode compartment as well as in the cathode compartment. The best performance, as determined bynitrate removal and nitrogen transfer into the gas phase, was reached with a specific current of 1.16 Am-2 for the laboratory apparatus and 1.53 A m-2 for the pilot plant apparatus. However, other parameterssuch as pH (influenced by anolyte solution) and catalyst selection also had an impact on the nitratereduction performance with the consequence that process optimization should be realized on-site whilerunning a pilot plant. Process gas analysis by mass spectroscopy revealed the presence of hydrogen,which suggests that a combination of the system with heterogeneous catalysts should be used foradditional nitrogen reduction at potential free surfaces.