Rubidium and Cesium Enediamide Complexes Derived from Bulky 1,4-Diazadienes

摘要

The first rubidium and cesium enediamide complexes based on bulky 1,4-diaza-1,3-diene ligands (DADs) have been prepared by metalation of either 1,4-bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene (1 , = ~(H2)DAD~(Dipp)) or 1,4-bis(2,6-diisopropylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene (2 , = ~(Me2)DAD~(Dipp)) with an excess of Rb or Cs metals in coordinating solvents such as tetrahydrofuran (THF) or 1,2-dimethoxyethane (DME). All new complexes were fully characterized by spectroscopic and analytical methods as well as single-crystal X-ray diffraction studies.