Modeling High-Pressure Methane Adsorption on Shales with a Simplified Local Density Model

摘要

Shale gas has attracted increasing attention as a potential alternative gas in recent years. Because a large fraction of gas in shale formation is in an adsorbed state, knowledge of the supercritical methane adsorption behavior on shales is fundamental for gas-in-place predictions and optimum gas recovery. A practical model with rigorous physical significance is necessary to describe the methane adsorption behavior at high pressures and high temperatures on shales. In this study, methane adsorption experiments were carried out on three Lower Silurian Longmaxi shale samples from the Sichuan Basin, South China, at pressures of up to 30 MPa and temperatures of 40, 60, 80, and 100 °C. The simplified local density/Elliott–Suresh–Donohue model was adopted to fit the experimental data in this study and the published methane adsorption data. The results demonstrate that this model is suitable to represent the adsorption data from the experiments and literature for a wide range of temperatures and pressures, and the average absolute deviation is within 10%. The methane adsorption capacity of the Longmaxi shale exhibited a strong linear positive correlation with the total organic carbon content and a linear negative correlation with increasing temperature. The rate of decrease in the methane adsorption capacity with swing temperature increased with the total organic carbon content, indicating that the organic matter is sensitive to temperature.