Adsorption Kinetics for CO2 Capture using Cerium Oxide Impregnated on Activated carbon

摘要

Various metal oxides of CeO 2 , ZnO, and Co 3 O 4 impregnated on activated carbon (AC) were synthesized to determine the CO 2 capture efficiency and analyse with adsorption kinetics model. Batch kinetic studies showed that CeO 2 /AC is the most efficient adsorbent with an equilibrium time of 10 minutes that was needed to obtain adsorption capacity of 52.68 mg/g. CO 2 adsorption at 30 °C exhibits the optimum temperature with only 6.53% loss in adsorption capacity after 5 cycles of CO 2 adsorption-desorption. The CeO 2 on AC was detected through X-ray diffraction and the scanning electron microscope image shows well-distributed CeO 2 particles on AC surfaces. CO 2 adsorption at 30 °C is best fitted with the pseudo-second-order kinetics with R 2 = 0.9994 and the relative error between calculated and experimental adsorption capacity only 1.32%. The adsorption considering chemisorption is responsible for improving adsorption capacity. The addition of CeO 2 on AC enhanced the adsorption capacity by providing active sites to attract CO 2 .