Platinized Graphene/ceramics Nano-sandwiched Architectures and Electrodes with Outstanding Performance for PEM Fuel Cells

摘要

For the first time a novel oxygen reduction catalyst with a 3D platinized grapheneano-ceramic sandwiched architecture is successfully prepared by an unusual method. Herein the specific gravity of graphene nanosheets (GNS) is tailored by platinizing graphene in advance to shorten the difference in the specific gravity between carbon and SiC materials, and then nano-SiC is well intercalated into GNS interlayers. This nano-architecture with highly dispersed Pt nanoparticles exhibits a very high oxygen reduction reaction (ORR) activity and polymer electrolyte membrane (PEM) fuel cell performance. The mass activity of half cells is 1.6 times of that of the GNS supported Pt, and 2.4 times that of the commercial Pt/C catalyst, respectively. Moreover, after an accelerated stress test our catalyst shows a predominantly electrochemical stability compared with benchmarks. Further fuel cell tests show a maximum power density as high as 747?mW/cm2 at low Pt loading, which is more than 2 times higher than that of fuel cells with the pristine graphene electrode.