Rapid and robust spatiotemporal dynamics of the first-order phase transition in crystals of the organic-inorganic perovskite (C₁₂H₂₅NH₃)₂PbI₄

摘要

The dynamics of the thermally induced first-order structural phase transition in a high-quality single crystal of the organic-inorganic perovskite (C₁₂H₂₅NH₃)₂PbI₄ was investigated by optical microscopy. The propagation of the straight phase front (habit plane) during the phase transition along the cooling and heating pathways of the thermal hysteresis was observed. The thermochromic character of the transition allowed monitoring of the thermal dependence of average optical density and aided the visualization of the interface propagation. The thermal hysteresis loop is 10?K wide, and the interface velocity is constant at V ≈?1.6?mm s–1. The transition is accompanied with sizeable change in crystal size, with elongation of ~6% along the b axis and compression of ~ –2% along the a axis, in excellent agreement with previously reported X-ray diffraction data. The progression of the habit plane is at least 160 times faster than in spin-crossover materials, and opens new prospects for organic-inorganic perovskites as solid switching materials. Moreover, the crystals of (C₁₂H₂₅NH₃)₂PbI₄ are unusually mechanically robust and present excellent resilience to thermal cycling. These hitherto unrecognized properties turn this and possibly similar hybrid perovskites into perspective candidates as active medium for microscopic actuation.