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Local structure controls the nonaffine shear and bulk moduli of disordered solids

机译:局部结构控制无序固体的非仿射剪切和体积模量

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Paradigmatic model systems, which are used to study the mechanical response of matter, are random networks of point-atoms, random sphere packings, or simple crystal lattices; all of these models assume central-force interactions between particles/atoms. Each of these models differs in the spatial arrangement and the correlations among particles. In turn, this is reflected in the widely different behaviours of the shear ( G ) and compression ( K ) elastic moduli. The relation between the macroscopic elasticity as encoded in G , K and their ratio, and the microscopic lattice structure/order, is not understood. We provide a quantitative analytical connection between the local orientational order and the elasticity in model amorphous solids with different internal microstructure, focusing on the two opposite limits of packings (strong excluded-volume) and networks (no excluded-volume). The theory predicts that, in packings, the local orientational order due to excluded-volume causes less nonaffinity (less softness or larger stiffness) under compression than under shear. This leads to lower values of G / K , a well-documented phenomenon which was lacking a microscopic explanation. The theory also provides an excellent one-parameter description of the elasticity of compressed emulsions in comparison with experimental data over a broad range of packing fractions.
机译:用于研究物质的机械响应的范式模型系统是点原子的随机网络,随机球体堆积或简单的晶格。所有这些模型都假定粒子/原子之间存在中心力相互作用。这些模型中的每个模型在空间排列和粒子之间的相关性方面都不同。反过来,这反映在剪切弹性模量(G)和压缩弹性模量(K)的行为上大不相同。以G,K编码的宏观弹性及其比率与微观晶格结构/顺序之间的关系尚不清楚。我们提供了具有不同内部微观结构的模型非晶态固体的局部取向顺序和弹性之间的定量分析联系,重点讨论了填料(强排阻体积)和网络(无排阻体积)的两个相反限制。该理论预测,在填料中,由于排除体积而导致的局部取向顺序导致的非亲和性(较小的柔软性或较大的刚度)在压缩下比在剪切下更少。这导致较低的G / K值,这是有据可查的现象,缺乏微观解释。与广泛填充分数范围内的实验数据相比,该理论还为压缩乳液的弹性提供了出色的一参数描述。

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