APS -APS March Meeting 2017 - Event - Entropic segregation of short chains to the surface of a polydisperse melt

摘要

It is well understood that chains ends have an entropic preference for the surface of a polymer melt, and consequently the shorter chains of a polydisperse melt are favored at the surface. We study this effect for a bidisperse melt using numerical self-consistent field theory (SCFT). Semi-analytical approximations to the SCFT are derived for the concentration profiles resulting in simple expressions for the integrated excess or depletion of each component.