Synthesis and evaluation of the SERS effect of Fe3O4–Ag Janus composite materials for separable, highly sensitive substrates

摘要

Fe _(3) O _(4) –Ag Janus composites were synthesized using a two-step solvothermal method. The optimal growth process was determined by investigating the relationship between the particle morphologies and reaction time. Magnetic and Raman spectroscopic measurements showed that the as-synthesized Janus composites have both good magnetic response and significant surface-enhanced Raman scattering (SERS) effects, as well as reproducibility. The calculated Raman enhancement factor reached an unprecedented magnitude of 10 ~(9) compared with the values of other Fe _(3) O _(4) –Ag compounds. Furthermore, the SERS effect was exhibited even at a concentration of probe molecules as low as 10 ~(?13) M. This demonstrates that the as-synthesized Fe _(3) O _(4) –Ag Janus composite particles have promise for application as separable, highly sensitive SERS substrates.