Sodium borohydride-nickel chloride hexahydrate in EtOH/PEG-400 as an efficient and recyclable catalytic system for the reduction of alkenes

摘要

An efficient, safe and one-pot convenient catalytic system has been developed for the reduction of alkenes using NaBH _(4) –NiCl _(2) ·6H _(2) O in EtOH/PEG-400 under mild conditions. In this catalytic system, a variety of alkenes (including trisubstituted alkene α-pinene) were well reduced and the Ni catalyst could be recycled.