A turn-on fluorescence sensor for the highly selective detection of Al3+ based on diarylethene and its application on test strips

摘要

A novel turn-on fluorescent sensor for Al ~(3+) based on photochromic diarylethene with a 2-hydroxybenzhydrazide unit has been successfully designed and synthesized. The photochromic and fluorescent characteristics were studied methodically in methanol under irradiation using UV/vis light and induced by Al ~(3+) /EDTA. This fluorescent sensor was highly selective toward Al ~(3+) with an obvious fluorescent color change from dark blue to blue. The Job's plot and mass spectrometry (MS) analysis indicate a binding stoichiometry of 1?:?1 between the fluorescent sensor and Al ~(3+) . Moreover, a test strip containing this fluorescent sensor was prepared to allow for the easy detection of Al ~(3+) in water. Finally, a logic circuit was designed using four input signals (In1: UV; In2: vis; In3: Al ~(3+) ; In4: EDTA) and one output signal.