Tables of proposed values for the Orientational Parameter of the Substituent I. Monoatomic, Diatomic, Triatomic, n-CnH2n+1, O-n-CnH2n+1, NRR

摘要

ABSTRACT Longtime ago, and from the analysis of the rotational partition function, a mathematical expression for the orientational parameters of the substituent was obtained [1, 2]. This parameter is purely geometrical and does not depend on any electronic property. As a preliminary physical interpretation we suggested that these terms represent the fraction of molecules attaining the proper orientation to interact with a given site. Given the necessity of having at hand "standard" numerical va.