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Solubility of potassium fluoride in aqueous solution at different temperatures 298.15K–353.15K

机译:不同温度下氟化钾在水溶液中的溶解度298.15K–353.15K

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In this investigation, the binary aqueous solutions of Potassium Fluoride have been studied using the hygrometric method at different temperatures 298.15K–353.15K. The water activities are measured at molalities from 0.10 mol kg−1 to saturation. The obtained data allow the deduction of osmotic coefficients. From these measurements, the ionic parameters are determined and used to predict the solute activity coefficients. Thermodynamic characteristics, solubility products K°sp and the standard molar Gibbs energy of dissolution ΔG°diss are given. The predicted solubility isotherms are compared with the literature data.
机译:在这项研究中,已使用湿度法在298.15K–353.15K的不同温度下研究了氟化钾的二元水溶液。水分活度的测量摩尔浓度为0.10 mol−kg-1至饱和。所获得的数据允许推导渗透系数。从这些测量中,确定离子参数并将其用于预测溶质活度系数。给出了热力学特性,溶解度乘积K°sp和标准摩尔Gibbs溶解能ΔG°diss。将预测的溶解度等温线与文献数据进行比较。

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