Composite MOFs as adsorbents for solid phase extraction combined with high performance liquid chromatography for the determination of polycyclic aromatic hydrocarbons in water

摘要

Metal-organic frameworks (MOFs) are a kind of porous materials, which has large specific surface area, high porosity, diverse structure, excellent thermal stability and solvent stability etc. So, it has attracted extensive attention as an adsorbent for solid phase extraction (SPE). Polycyclic aromatic hydrocarbons (PAHs) are a kind of persistent organic pollutants that can lead serious hurts to the ecological environment and human health. The purpose of this paper is to optimize the types and proportion of mixed lanthanum based MOFs, and to improve the enrichment efficiency of SPE. Then a method to analysis PAHs by SPE-HPLC was established. Several main factors that could effected the pre-treatment efficient, such as the amount of adsorbent, the amount and pH of PAHs water sample, and the volume of eluent, were investigated. After optimized, the extraction of seven PAHs in water sample was achieved and the recovery rates were 80.67%, 80.06%, 54.69%, 82.62%, 118.87%, 70.30% and 95.57% respectively.