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Modelling and simulation of a slurry bubble column reactor for green fuel production via hydrocracking of vegetable oil

机译:用于植物油加氢裂化生产绿色燃料的浆料鼓泡塔反应器的建模与仿真

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A slurry bubble column reactor to produce green fuel through hydrocracking of vegetable oil with Ni-W/SiO_(2)-Al_(2)O_(3)catalyst was simulated in this research with the objectives being to obtain a mathematical model of the reactor and an optimum operation condition. The steady state two-dimensional axisymmetric model of the slurry bubble column reactor with the diameter of 2.68 m and height of 7.14 m was modelled by considering mass and heat transfers. The very small liquid superficial velocity reflects that the liquid phase is in batch-like operation. The gas of 0.01 m/s in superficial velocity flows upward to suspend and agitate the spherical catalyst particles of 100 μm in diameter inside the reactor. The reactor operated at 80 bar and 420°C. Triglyceride of 5% w/w in dodecane and hydrogen of 105.5 mol hydrogen/triglyceride enter the reactor from the bottom. The research also considered pressure drop and loading catalyst distribution inside the reactor. Simulation results show that the triglyceride conversion is 99.26%, the product yield is 40.68% w/w, and the product purity is 45.55% w/w.
机译:本研究以Ni-W / SiO_(2)-Al_(2)O_(3)催化剂加氢裂化植物油为原料的浆式鼓泡塔反应器为模型,以得到反应器的数学模型。以及最佳的操作条件。通过考虑传质和传热,建立了直径为2.68 m,高度为7.14 m的浆态鼓泡塔反应器的稳态二维轴对称模型。很小的液体表面速度反映出液相处于间歇式操作中。表面速度为0.01 m / s的气体向上流动,以悬浮并搅拌反应器内部直径为100μm的球形催化剂颗粒。反应器在80巴和420℃下操作。十二烷中5%w / w的甘油三酸酯和105.5 mol氢/甘油三酸酯的氢从底部进入反应器。该研究还考虑了反应器内部的压降和负载催化剂分布。模拟结果表明,甘油三酸酯的转化率为99.26%,产物收率为40.68%w / w,产物纯度为45.55%w / w。

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