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首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.02,6]dec-8-ene-3,5-dione
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Crystal structure of 1,7,8,9-tetra­chloro-4-(3,5-di­chloro­benz­yl)-10,10-dimeth­oxy-4-aza­tri­cyclo­[5.2.1.02,6]dec-8-ene-3,5-dione

机译:1,7,8,9-四氯-4-(3,5-二氯苄基)-10,10-二甲氧基-4-氮杂三环[5.2.1.02,6] dec-8-ene-3,5-二酮的晶体结构

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摘要

In the title compound, C17H11Cl6NO4, the configuration of the cyclo­alkene skeleton is endo,cis. The benzene ring is twisted by 58.94 (8)° from the attached pyrrolidine ring. Two carbonyl groups play a key role in the crystal packing. A short inter­molecular C⋯O distance of 3.017 (3) Å reveals that one carbonyl group is involved in dipole–dipole inter­actions, which link two adjacent enanti­omers into an inversion dimer. Another carbonyl group provides an acceptor for the weak inter­molecular C—H⋯O hydrogen bonds which link these dimers into layers parallel to (011).
机译:在标题化合物C17H11Cl6NO4中,环烯烃骨架的构型是内顺式。苯环从连接的吡咯烷环上扭曲58.94(8)°。两个羰基在晶体堆积中起关键作用。分子间的短C O距离为3.017(3)Å,表明一个羰基参与偶极-偶极相互作用,将两个相邻的对映异构体连接成一个反向二聚体。另一个羰基为弱分子间的CHH = O氢键提供一个受体,该键将这些二聚体连接成与(011)平行的层。

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