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首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of 11-(2,3-di­meth­oxy­phen­yl)-14-methyl-12-oxa-8,14-di­aza­tetra­cyclo­[8.3.3.01,10.02,7]hexa­deca-2(7),3,5-triene-9,13-dione
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Crystal structure of 11-(2,3-di­meth­oxy­phen­yl)-14-methyl-12-oxa-8,14-di­aza­tetra­cyclo­[8.3.3.01,10.02,7]hexa­deca-2(7),3,5-triene-9,13-dione

机译:11-(2,3-二甲氧基苯基)-14-甲基-12-氧杂-8,14-二氮杂四环[8.3.3.01,10.02,7]十六碳-2(7),3,5-三烯-9的晶体结构, 13二酮

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摘要

The title compound, C22H22N2O5, contains two conformationally similar mol­ecules (A and B) in its the asymmetric unit (r.m.s. overlay fit for the 29 non-H atoms = 0.194 Å). In each mol­ecule, the lactone ring has an envelope conformation with the spiro C atom as the flap. In the crystal, A+A and B+B inversion dimers linked by pairs of N—H⋯O hydrgen bonds occur; in both cases, R22(8) loops are generated. A weak C—H⋯O inter­action is also observed, which links the dimers into [010] chains.
机译:标题化合物C 22 H 22 N 2 O 5在其不对称单元中具有两个构象相似的分子(A和B)(对29个非H原子的r.m.s.重叠拟合= 0.194Å)。在每个分子中,内酯环具有作为螺线的螺C原子的包膜构象。在晶体中,出现了由N-H = O氢键对连接的A + A和B + B反转二聚体;在这两种情况下,都会生成R22(8)循环。还观察到弱的CHOH相互作用,其将二聚体连接到[010]链中。

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