[2-({Benz-yl[2-(benz-yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth-yl)imino-meth-yl]benz-yl}amino)-eth-yl]aza-nium-yl}meth-yl)-4-methyl-6-[(pyridin-2-ylmeth-yl)imino-meth-yl]phenolato]nickel(II) perchlorate methanol disolvate

摘要

In the solvated title complex, [Ni(C46H47N6O2)]ClO4·2CH4O, the coordination sphere around the NiII ion can be described as distorted cis-NiO2N4 octa-hedral defined by two phenolate O atoms and four N atoms from the hexa-dentate ligand. An intra-molecular bifurcated N—H?(N,O) hydrogen bond helps to establish the conformation of the complex mol-ecule. In the crystal, the components are connected by O—H?O and C—H?O hydrogen bonds.